Correlation between the activation enthalpy and Kohlrausch exponent for ionic conductivity in oxide glasses

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Correlation between the activation enthalpy and Kohlrausch exponent for ionic conductivity in oxide glasses.

We have established for alkali ions in oxide glasses a strong correlation between the fractional (Kohlrausch) exponent β in the conductivity relaxation function, exp[-(t/τ*)β], and the activation energy E*a of τ* and σ when varying the composition of oxide glass formers and the alkali ions while holding the alkali-ion concentration constant. An even stronger correlation of the trends in β and t...

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ژورنال

عنوان ژورنال: Physical Review B

سال: 1989

ISSN: 0163-1829

DOI: 10.1103/physrevb.40.10550